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Vadose zone nitrate contained within cave drip waters and speleothems

This data set contains a record of nitrate concentrations and isotopic composition present within the drip waters and speleothem carbonate deposits of Cueva-cubío del Llanío, northern Spain. Data were collected between 2018 to 2020, and specifically address the nitrate composition of the cave drip waters, pool waters, rocks, soil, vegetation and contemporary speleothem carbonate. Calculations are also undertaken to assess the partitioning of nitrate between cave drip water and speleothem carbonate deposits. Data pertaining to speleothem nitrate content also extend to other cave locations (Pooles cavern, UK; Brown's Folly Mine, UK, Ease Gill Caverns, UK; Rukiesa cave, Ethiopia; Cueva Perlas, N. Spain). Sample analysis was performed at Lancaster University and the UK Centre for Ecology and Hydrology under NERC facility access grant LSMSF\CEH\L\125\11\2018. The data presented represent the full underlying dataset to Wynn et al., 2021, Chemical Geology: DOI.org/10.1016/j.chemgeo.2021.120172.

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Identification info

Metadata Language
English (en)
Dataset Reference Date ()
2021-03-19
Identifier
http://data.bgs.ac.uk/id/dataHolding/13607723
  University of Lancaster - Dr Peter Wynn ( Reader in Physical Geography )
Lancaster Environment Centre , Lancaster , LA1 4YQ , United Kingdom
  University of Lancaster - Scott Ambler ( Research Student )
Lancaster Environment Centre , Lancaster , LA1 4YQ ,
  University of Lancaster - Dr. Imke Grefe ( International Lecturer )
Lancaster Environment Centre , Lancaster , LA1 4YQ ,
  UK Centre for Ecology and Hydrology - Dr. David Soto ( Team Leader )
Lancaster , LA1 4AP ,
  UK Centre for Ecology and Hydrology - Dr. Helen Grant ( Stable Isotope Analyst )
Lancaster , LA1 4AP ,
  British Geological Survey - Enquiries
  British Geological Survey - Enquiries
Maintenance and update frequency
notApplicable
GEMET - INSPIRE themes
  • Geology
BGS Thesaurus of Geosciences
  • Isotopes
  • Nitrates
  • Speleothems
Keywords
  • NERC_DDC
Limitations on Public Access
otherRestrictions
Other constraints
licenceOGL
Other constraints
Available under the Open Government Licence subject to the following acknowledgement accompanying the reproduced NERC materials "Contains NERC materials ©NERC [year]"
Use constraints
otherRestrictions
Other constraints
The copyright of materials derived from the British Geological Survey's work is vested in the Natural Environment Research Council [NERC]. No part of this work may be reproduced or transmitted in any form or by any means, or stored in a retrieval system of any nature, without the prior permission of the copyright holder, via the BGS Intellectual Property Rights Manager. Use by customers of information provided by the BGS, is at the customer's own risk. In view of the disparate sources of information at BGS's disposal, including such material donated to BGS, that BGS accepts in good faith as being accurate, the Natural Environment Research Council (NERC) gives no warranty, expressed or implied, as to the quality or accuracy of the information supplied, or to the information's suitability for any use. NERC/BGS accepts no liability whatever in respect of loss, damage, injury or other occurence however caused.
Other constraints
Available under the Open Government Licence subject to the following acknowledgement accompanying the reproduced NERC materials "Contains NERC materials ©NERC [year]"
Spatial representation type
textTable
Topic category
  • Geoscientific information
Extent
ES

Dataset Reference Date ()
2009

Extent
ESP

Dataset Reference Date ()
2009

Extent
GB

Dataset Reference Date ()
2009

Extent
SPAIN [id=248000]

Dataset Reference Date ()
1979

Extent
UK [id=139300]

Dataset Reference Date ()
1979

Extent
UKM

Dataset Reference Date ()
2009

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Begin date
2018-01-20
End date
2020-08-20
 

Spatial Reference System

No information provided.

Distribution Information

Data format
  • csv ()

Resource Locator
Data
Resource Locator
Published Paper
Resource Locator
Digital Object Identifier (DOI)
Resource Locator
Data
Resource Locator
Published Paper
Resource Locator
Digital Object Identifier (DOI)
 
Quality Scope
dataset
Other
dataset

Report

Dataset Reference Date ()
2011
Explanation
See the referenced specification
Degree

Report

Dataset Reference Date ()
2010-12-08
Explanation
See http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2010:323:0011:0102:EN:PDF
Degree
Statement
Cave waters, vegetation, rocks and soils were collected through repeat sampling trips to the Cueva-cubío del Llanío cave site throughout 2018 to 2020. Modern calcite was grown on glass plates sited within the cave over time intervals of 6 to 18 months. Water samples were analysed for nitrate content using automated colourimetry. Nitrogen percentage and isotope composition of soils, sediments and vegetation were determined by elemental analyser linked to an isotope ratio mass spectrometer at Lancaster University. The nitrate isotope composition of cave waters and speleothem carbonate were determined using the microbial denitrification of sample nitrate to nitrous oxide gas with subsequent analysis by isotope ratio mass spectrometry within the National Environmental Isotope Facility hosted by the UK Centre for Ecology and Hydrology.

Metadata

File identifier
be32f45f-cbe2-5d1e-e054-002128a47908 XML
Metadata Language
English (en)
Resource type
dataset
Metadata Date
2023-03-27
Metadata standard name
UK GEMINI
Metadata standard version
2.3
  British Geological Survey
Environmental Science Centre,Keyworth , NOTTINGHAM , NOTTINGHAMSHIRE , NG12 5GG , United Kingdom
+44 115 936 3100
 
 

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