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A new synthetic method for studying phase behaviour is described using Attenuated Total Reflection (ATR) spectroscopy. The method has been developed to provide relevant information on the solubility of water in CO2. The dew point of water has been determined at three different pressures, viz. (4.05, 5.05 and 6.03) MPa with mole fractions of water between 0.01 and 0.04. The data obtained fill the gap in the literature in these regions of pressures and temperatures and could be of high importance in the context of Carbon Capture and Storage (CCS) technology. Indeed, the presence of water in the captured CO2 could damage the pipeline used for CO2 transport. Hence, it is very important to have a fully understanding of the behaviour of the (CO2 + H2O) mixtures in wide range of temperature relevant for CCS. The paper is available at http://www.sciencedirect.com/science/article/pii/S0021961415003547, DOI: 10.1016/j.jct.2015.09.024. UKCCSRC Grant UKCCSRC-C2-185.
The RISCS guide summarises the conclusions and recommendations developed by the RISCS Consortium, based on four years of research into the potential impacts of leakage from CO2 storage sites. The report has been developed in parallel with the experimental research, field-based investigations, modelling studies and analysis undertaken during the RISCS project. The Report can be downloaded from http://www.riscs-co2.eu/UserFiles/file/RISCS_Guide/RISCS_Guide.pdf.
The data consists of an extended abstract submitted to 'The Fourth International Conference on Fault and Top Seals', Almeria, Spain, 20-24th September 2015. The abstract describes work carried-out on behalf of the 'Fault seal controls on CO2 storage capacity in aquifers' project funded by the UKCCS Research Centre, grant number UKCCSRC-C1-14. The CO2-rich St. Johns Dome reservoir in Arizona provides a useful analogue for leaking CO2 storage sites, and the abstract describes an analysis of the fault-seal behaviour at the site. http://earthdoc.eage.org/publication/publicationdetails/?publication=82673.
Publications linked to the Grant: Holwell DA, Keays RR, McDonald I and Williams MR. 2015. Extreme Enrichment of Se, Te, PGE and Au in Cu sulfide microdroplets: evidence from LA-ICP-MS analysis of sulfides in the Skaergaard Intrusion, East Greenland Contribution to Mineralogy and Petrology. doi: 10.1007/s00410-015-1203-y. 2) Smith JW, Holwell DA, McDonald I, Boyce AJ. 2016. The application of S isotopes and S/Se ratios in determining ore-forming processes of Magmatic Ni-Cu-PGE sulfide deposits: a cautionary case study from the northern Bushveld Complex Ore Geology Reviews, 73, 148–174 10.1016/j.oregeorev.2015.10.022. Jenkin GRT, Al-Bassam AZM, Harris, RC, Abbott, AP, Smith DJ, Holwell DA, Chapman RJ and Stanley CJ. 2015. The application of Deep Eutectic Solvent Ionic liquids for environmentally friendly dissolution and recovery of precious metals. Minerals Engineering, doi: 10.1016/j.mineng.2015.09.026. Hughes, H. S.R., McDonald, I., Faithfull, J. W., Upton, B. G..J., and Loocke, M. (2016) Cobalt and precious metals in sulphides of Peridotite Xenoliths and inferences concerning their distribution according to geodynamic environment: a case study from the Scottish lithospheric mantle. Lithos, 240-3, pp. 202-227. doi:10.1016/j.lithos.2015.11.007. Abbott, A.P., Harris, R.C., Holyoak, F., Frisch, G., Hartley, J. and Jenkin, G.R., 2015. Electrocatalytic recovery of elements from complex mixtures using Deep Eutectic solvents. Green Chemistry, 17(4), pp.2172-2179. DOI: 10.1039/C4GC02246G
Bibliographic Data - Oral and Poster Presentations given by members of Work Package 5 of the HydroFrame (Hydromechanical and Biogeochemical Processes in Fractured Rock Masses in the Vicinity of a Geological Disposal Facility for Radioactive Waste) project. Presentations given between November 2014 and November 2016.
This dataset contains numerical model output of a morphodynamic and sedimentological simulation of a large river confluence based loosely on the Jamuna-Ganges junction in Bangladesh. The work was carried out as part of a joint project between the Universities of Birmingham, Southampton and Exeter. "The sedimentology of fluvial megascours" was a scientific research project funded by NERC. One aspect of the project was to undertake numerical simulations (the data described here) with which to compare with river bed bathymetry data (collected using a multibeam echosounder) and sub bottom seismic profiling data (collected using a surface tow boomer and chirp system). The data has been accepted for a publication in the journal 'Sedimentology' which will be published in 2018 with the title 'The Sedimentology of channel confluences'.
Graphite software drawings of hydrothermal Atomic Force Microscopy (AFM) parts. Each part is on a different file. Complete housing assembly drawing shows stacking of all different part on assembled AFM. BMP files provided for quick browsing in the absence of graphite software.
Synchrotron X-radiography (images) and diffraction data collected to measure rheology of Quartz coesite and stishovite.
Synchrotron X-radiography (images) and diffraction data collected to measure anelasticity of zinc. NERC grant NE/H016309/1 - Experimental determination of mantle rheology. NERC grant NE/L006898/1 - The strength of the lower mantle.
These data files represent simulations of hydrated cation vacancies in the mantle mineral forsterite (Mg2SiO4) undertaken using the CASTEP atomic scale simulation code (http://www.castep.org/). Results from these simulations allow the structure relative stability of different defect configurations to be compared. Three types of cation vacancies are considered (M1, M2 and Si) each decorated by hydrogen in order to charge balance the system. For M1 and M2 this results in multiple configurations (with hydrogen bonded to different oxygen atoms around the vacant site). For Si there is only one configuration as all four oxygen atoms are bonded to hydrogen for the charge neutral defect. For each configuration input files detail the initial atomic structure of the defect along with simulation parameters. Output files record the progress of the simulation, the final atomic structure, the energy of this structure, and various predicted properties of the structure. Only ASCII output data is included as binary data created by CASTEP is not intended to be portable, and can easily be recreated using the ASCII files.