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This file documents the sulphur isotope data, and the manner in which it has been processed, to supply the reference data for isotope domains of the Isotope biosphere domains GB (V1) map. It includes a summary of the analytical methods used to determine the isotope ratios though time.
These datasets provide Concentration Based Estimated Deposition (CBED) values of sulphur and nitrogen atmospheric deposition for 5x5 kilometres (km) grid squares of the UK averaged over the years 2017 to 2019. The data consist of deposition values for sulphur, oxidised nitrogen and reduced nitrogen, and base cations. Total deposition is the sum of four components calculated separately: wet deposition, dry deposition of gases, dry deposition of particulate matter and cloud droplet deposition. Habitat-specific data are provided for (i) moorland/short vegetation everywhere, and (ii) forest everywhere. Additionally, the grid square average over multiple land cover types (i.e. arable, grassland, forest, moorland, urban) is also calculated. The habitat-specific data are recommended for use with critical loads for the calculation of critical load exceedances. The work in generating and compiling the dataset has been funded by the UK Centre for Ecology & Hydrology (UKCEH) and various Departments for Environment, Food & Rural Affairs (Defra) contracts. Full details about this dataset can be found at https://doi.org/10.5285/1efa692d-76ca-406e-8736-837a457e16ee
This dataset provides values of sulphur and nitrogen deposition, deposition of non-marine base cations and concentration values for ammonia (NH3), sulphur dioxide (SO2) and nitrogen oxide (NOx) on the UK nature conservation protected sites, averaged over the years 2017 to 2019. The dataset also includes calculated minimum, maximum and gridded average values for each site. Protected nature sites covered are: (i) Special Areas of Conservation (SAC) (ii) Special Protection Areas (SPA) (iii) Sites of Special Scientific Interest (SSSI). The data consist of values of nitrogen and acid deposition, non-marine base cation deposition, and concentrations of ammonia (NH3) based on the Concentration Based Estimated Deposition (CBED), and concentrations of NOx and SO2 using the Pollution Climate Mapping (PCM) model. Nitrogen and acid deposition data is also given for specific habitat types including: (i) moorland/short vegetation everywhere, (ii) forest everywhere, and (iii) the grid square average over multiple land cover types (i.e. arable, grassland, forest, moorland, urban) These habitat-specific data are recommended for use with critical loads for the calculation of critical load exceedances using the relevant deposition/habitat type. Full details about this dataset can be found at https://doi.org/10.5285/65ab44a0-58bd-43ab-a3bc-a850ddd9a0f1
Pyrite samples from selected sedimentary organic-rich formations or associated igneous and metamorphic rocks were analysed by conventional S isotopic analysis. Pyrites were measured in order to provide insights into their origin. Light and variable S isotope compositions in pyrite have been used to infer the influence of sulphate-reducing bacteria (and subsequent Se precipitation by sulphate-reducing microbes), whereas heavier S isotope compositions indicate a non-biological origin (i.e. physical and chemical diagenesis).
This dataset contains nitrogen data from nitrate, ammonium and nitrite, total nitrogen and carbon data, and elemental composition data from anaerobic digestate and biomass ash from UK bioenergy production. Anaerobic digestate was sampled 8 times from different industrial scale plants across the UK between January 2015 and January 2018 and biomass ash was sampled in January 2015 and June 2016. Anaerobic digestate was sourced from segregated food waste (mainly household waste), pig slurry, maize silage, vegetables waste, sweet corn waste, aerobically treated food waste, food manufacturer waste and other biodegradable sludge from within the UK. Biomass ash, both fly and bottom ash, from virgin and recycled wood was sourced from three sites within the UK and one from Spain. All laboratory analyses were undertaken at Lancaster University using standardised methods. The data were collected as part of the research grant, Developing a suite of novel land conditioners and plant fertilizers from the waste streams of biomass energy generation. The research was funded by NERC, award NE/L014122/1. Full details about this dataset can be found at https://doi.org/10.5285/990c54f6-5c92-4054-8bfa-953533a89149
CEH Land Cover plus: Pesticides maps annual average pesticide applications across England, Wales and Scotland. The product provides application estimates for 162 different active ingredients including herbicides, insecticides, molluscicides and fungicides. It is produced at a 1km resolution with units of kg active ingredient applied per year, averaged between 2012 and 2017. Pesticide application rates (kg/km2/yr) are calculated for each of the crops grown in each 1km square, using information from CEH Land Cover® Plus: Crops 2015, 2016 and 2017 to determine where each crop is grown. Pesticide application data is provided by the Pesticide Usage Survey. Uncertainty maps are produced alongside each active ingredient map to quantify the level of confidence in the estimated applications. Uncertainty is quantified using the distribution of each parameter estimate obtained from the modelling method and is expressed relative to the total application. The product builds upon the Centre for Ecology & Hydrology (CEH) Land Cover® Plus: Crops product. These maps were created under the NERC funded ASSIST (Achieving Sustainable Agricultural Systems) project to enable exploration of the impacts of agrochemical usage on the environment, enabling farmers and policymakers to implement better, more sustainable agricultural practices. Full details about this dataset can be found at https://doi.org/10.5285/99a2d3a8-1c7d-421e-ac9f-87a2c37bda62